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Caesium fluoride

Cesium fluoride

CAS: 13400-13-0

Molecular Formula: CsF

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Caesium fluoride - Names and Identifiers

Name Cesium fluoride
Synonyms LT-E004
Cesium fluoride
caesium fluoride
CsF, CesiuM fluoride
Anti-Laminin B2t chain
Anti-CSF 140 kDa subunit
Anti-Ladsin 140 kDa subunit
Anti-Laminin subunit gamma-2
Anti-Laminin 5 gamma 2 subunit
CAS 13400-13-0
EINECS 236-487-3
InChI InChI=1/Cs.FH/h;1H/q+1;/p-1
InChIKey XJHCXCQVJFPJIK-UHFFFAOYSA-M

Caesium fluoride - Physico-chemical Properties

Molecular FormulaCsF
Molar Mass151.9
Density4.115g/mLat 25°C(lit.)
Melting Point682°C(lit.)
Boling Point1251 °C
Flash Point1251°C
Water Solubility369 g/100 mL (18 ºC)
Solubility H2O: 3M at20°C, clear, colorless
Vapor Presure0Pa at 25℃
AppearancePowder/Lump
Specific Gravity4.115
ColorWhite
Exposure LimitACGIH: TWA 2.5 mg/m3NIOSH: IDLH 250 mg/m3; TWA 2.5 mg/m3
Maximum wavelength(λmax)['λ: 260 nm Amax: 0.05',
, 'λ: 280 nm Amax: 0.05']
Merck14,2012
PH6.5-7.5 (25℃, 3M in H2O)
Storage Condition0-6°C
Stabilityhygroscopic
SensitiveHygroscopic
UseUsed as an analytical reagent, but also for the manufacture of optical crystals

Caesium fluoride - Risk and Safety

Risk CodesR23/24/25 - Toxic by inhalation, in contact with skin and if swallowed.
R34 - Causes burns
R62 - Possible risk of impaired fertility
R41 - Risk of serious damage to eyes
R38 - Irritating to the skin
R32 - Contact with acids liberates very toxic gas
Safety DescriptionS26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection.
S45 - In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
UN IDsUN 2923 8/PG 2
WGK Germany3
RTECSFK9650000
FLUKA BRAND F CODES3-10
TSCAT
HS Code28261990
Hazard NoteCorrosive
Hazard Class6.1
Packing GroupIII

Caesium fluoride - Reference Information

LogP0.23 at 20℃
NIST chemical information information provided by: webbook.nist.gov (external link)
EPA chemical substance information information provided by: ofmpeb.epa.gov (external link)
solubility in water (g/100ml) grams dissolved per 100ml of water: 322g/20 ℃
Use is used as an analytical reagent and also in the production of optical crystals
for the production of fluorine-containing isocyanates.
in the Suzuki cross-coupling synthesis reaction, as a base, used for the positive substitution of biaryl; also as a nucleophile for the fluorination of primary halides and sulfonates in protic media such as tert-butyl or tert-amyl alcohols; As a catalyst for the reaction of silanol ethers with carbonyl compounds; for the effective synthesis of single crystal Dion-Jacobson phase csrata2o7, applied in photocatalysis and superconductivity
category toxic substances
toxicity grade poisoning
Acute toxicity Reference range: oral-rat LD50: 2600 mg/kg; Oral-mouse LD50: 2306 mg/kg
flammability hazard characteristics non-combustible; Toxic hydrogen fluoride gas emitted in case of acid; toxic fluoride and cesium oxide fumes from heat
storage and transportation characteristics The warehouse is ventilated and dried at low temperature; It is stored separately from acids and food additives
Occupational Standard TLV-TWA 2.5 mg (fluorine)/m3; Tel 5 mg (fluorine)/M3
Last Update:2024-04-10 22:29:15
Caesium fluoride
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View History
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